Thermodynamics of n-component systems (n<6): calorimetric measurements and estimation of enthalpies of formation
Identifieur interne : 018339 ( Main/Repository ); précédent : 018338; suivant : 018340Thermodynamics of n-component systems (n<6): calorimetric measurements and estimation of enthalpies of formation
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Copyright (c) 1996 Elsevier Science B.V. All rights reserved. The enthalpies of formation (&Dgr;mixH°m) of the [Bi+Cd+Ga+Zn, [Bi+Cd+Ga+In+Zn and [Bi+Cd+Ga+In+Sn+Zn liquid alloys were measured at 730K by additions of a solid metal (Bi, Cd, In, Sn) to the equimolar sub systems [Bi+Ga+Zn, [Cd+Ga+Zn, [Bi+Cd+Ga+Zn, [Cd+Ga+In+Zn, [Cd+Ga+In+Sn+Zn, [Bi+Cd+Ga+In+Zn. Simultaneously, these enthalpies (&Dgr;mixH°m) were calculated by using the Hoch-Arpshofen (HA) model and published data of the enthalpies of formation of the limiting binary systems. The agreement between calculated and measured values is good in respect of the accuracy (i) of the experimental technique (direct calorimetry) and (ii) of the thermodynamic data of the sub-systems. Thus, the HA model allows the excess molar thermodynamic functions of formation of the six-component liquid alloys to be correctly predicted.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Thermodynamics of n-component systems (n<6): calorimetric measurements and estimation of enthalpies of formation</title><author><name sortKey="Ouedraogo, R" uniqKey="Ouedraogo R">R. Ouedraogo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>University of Ouagadougou</s1><s2>Ouagadougou</s2><s3>BFA</s3><sZ>1 aut.</sZ></inist:fA14><country>Burkina Faso</country><wicri:noRegion>University of Ouagadougou</wicri:noRegion></affiliation></author><author><name sortKey="Gambino, M" uniqKey="Gambino M">M. Gambino</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>University of Provence, IUSTI-CNRS UMR 139, Av. Escadrille Normandie-Niemen, F-13397</s1><s2>Marseille</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="région">Provence-Alpes-Côte d'Azur</region><settlement type="city">Marseille</settlement></placeName></affiliation></author><author><name sortKey="Bros, J P" uniqKey="Bros J">J. P. Bros</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>University of Provence, IUSTI-CNRS UMR 139, Av. Escadrille Normandie-Niemen, F-13397</s1><s2>Marseille</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="région">Provence-Alpes-Côte d'Azur</region><settlement type="city">Marseille</settlement></placeName></affiliation></author><author><name sortKey="Hoch, M" uniqKey="Hoch M">M. Hoch</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>University of Cincinatti, College of Engineering, Department of Materials Science and Metallurgical Engineering</s1><s2>Cincinatti</s2><s3>USA</s3><sZ>4 aut.</sZ></inist:fA14><country>États-Unis</country><wicri:noRegion>Cincinatti</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">97-0218355</idno><date when="1997">1997</date><idno type="stanalyst">PASCAL 97-0218355 Elsevier</idno><idno type="RBID">Pascal:97-0218355</idno><idno type="wicri:Area/Main/Corpus">019D92</idno><idno type="wicri:Area/Main/Repository">018339</idno></publicationStmt><seriesStmt><idno type="ISSN">0925-8388</idno><title level="j" type="abbreviated">J. alloys compd.</title><title level="j" type="main">Journal of alloys and compounds</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bismuth</term><term>Cadmium</term><term>Calorimetry</term><term>Enthalpy</term><term>Experimental study</term><term>Formation heat</term><term>Gallium</term><term>Indium</term><term>Liquid alloy</term><term>Multi-element alloys</term><term>Multidimensional system</term><term>Thermodynamic model</term><term>Thermodynamic properties</term><term>Tin</term><term>Zinc</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Propriété thermodynamique</term><term>Calorimétrie</term><term>Système n dimensions</term><term>Chaleur formation</term><term>Alliage multiélément</term><term>Enthalpie</term><term>Alliage liquide</term><term>Bismuth</term><term>Cadmium</term><term>Gallium</term><term>Etain</term><term>Modèle thermodynamique</term><term>Etude expérimentale</term><term>Zinc</term><term>Indium</term><term>6550</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Bismuth</term><term>Cadmium</term><term>Zinc</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Copyright (c) 1996 Elsevier Science B.V. All rights reserved. The enthalpies of formation (&Dgr;<sub>mix</sub>H<sup>°</sup><sub>m</sub>) of the [Bi+Cd+Ga+Zn, [Bi+Cd+Ga+In+Zn and [Bi+Cd+Ga+In+Sn+Zn liquid alloys were measured at 730K by additions of a solid metal (Bi, Cd, In, Sn) to the equimolar sub systems [Bi+Ga+Zn, [Cd+Ga+Zn, [Bi+Cd+Ga+Zn, [Cd+Ga+In+Zn, [Cd+Ga+In+Sn+Zn, [Bi+Cd+Ga+In+Zn. Simultaneously, these enthalpies (&Dgr;<sub>mix</sub>H<sup>°</sup><sub>m</sub>) were calculated by using the Hoch-Arpshofen (HA) model and published data of the enthalpies of formation of the limiting binary systems. The agreement between calculated and measured values is good in respect of the accuracy (i) of the experimental technique (direct calorimetry) and (ii) of the thermodynamic data of the sub-systems. Thus, the HA model allows the excess molar thermodynamic functions of formation of the six-component liquid alloys to be correctly predicted.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0925-8388</s0></fA01><fA03 i2="1"><s0>J. alloys compd.</s0></fA03><fA05><s2>247</s2></fA05><fA06><s2>1-2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Thermodynamics of n-component systems (n<6): calorimetric measurements and estimation of enthalpies of formation</s1></fA08><fA11 i1="01" i2="1"><s1>OUEDRAOGO (R.)</s1></fA11><fA11 i1="02" i2="1"><s1>GAMBINO (M.)</s1></fA11><fA11 i1="03" i2="1"><s1>BROS (J. P.)</s1></fA11><fA11 i1="04" i2="1"><s1>HOCH (M.)</s1></fA11><fA14 i1="01"><s1>University of Ouagadougou</s1><s2>Ouagadougou</s2><s3>BFA</s3><sZ>1 aut.</sZ></fA14><fA14 i1="02"><s1>University of Provence, IUSTI-CNRS UMR 139, Av. Escadrille Normandie-Niemen, F-13397</s1><s2>Marseille</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="03"><s1>University of Cincinatti, College of Engineering, Department of Materials Science and Metallurgical Engineering</s1><s2>Cincinatti</s2><s3>USA</s3><sZ>4 aut.</sZ></fA14><fA20><s1>180-184</s1></fA20><fA21><s1>1997</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA24 i1="01"><s0>eng</s0></fA24><fA43 i1="01"><s1>INIST</s1><s2>1151</s2><s5>354000063228960052</s5></fA43><fA44><s0>9000</s0><s1>© 1997 Elsevier Science B.V. All rights reserved.</s1></fA44><fA47 i1="01" i2="1"><s0>97-0218355</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal of alloys and compounds</s0></fA64><fA66 i1="01"><s0>CHE</s0></fA66><fC01 i1="01" l="ENG"><s0>Copyright (c) 1996 Elsevier Science B.V. All rights reserved. The enthalpies of formation (&Dgr;<sub>mix</sub>H<sup>°</sup><sub>m</sub>) of the [Bi+Cd+Ga+Zn, [Bi+Cd+Ga+In+Zn and [Bi+Cd+Ga+In+Sn+Zn liquid alloys were measured at 730K by additions of a solid metal (Bi, Cd, In, Sn) to the equimolar sub systems [Bi+Ga+Zn, [Cd+Ga+Zn, [Bi+Cd+Ga+Zn, [Cd+Ga+In+Zn, [Cd+Ga+In+Sn+Zn, [Bi+Cd+Ga+In+Zn. Simultaneously, these enthalpies (&Dgr;<sub>mix</sub>H<sup>°</sup><sub>m</sub>) were calculated by using the Hoch-Arpshofen (HA) model and published data of the enthalpies of formation of the limiting binary systems. The agreement between calculated and measured values is good in respect of the accuracy (i) of the experimental technique (direct calorimetry) and (ii) of the thermodynamic data of the sub-systems. 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